Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III)
نویسندگان
چکیده
In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N',O,O'-chelated by a 6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, and one Cl(-) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol mol-ecules and two Cl(-) anions in an bicapped trigonal-prismatic geometry. Intra- and inter-molecular O-H⋯Cl hydrogen bonds are present in the structure.
منابع مشابه
{6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
In the title compound, [Cu(C22H24N2O4)]·H2O, the Cu(II) atom is four-coordinated in a distorted planar geometry with a mean deviation of 0.1164 (2) Å for the plane generated by the ligating atoms of the salen-type Schiff base ligand. In the crystal, O(water)-H⋯O and C-H⋯O hydrogen bonds form a three-dimensional-network.
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